The main issue with that is that by the time it'd come to that (I don't recall how willing he is to use it in comparison to Gil) Kakine would've likely spread DM all across the battlefield (and possibly even some on Enkidu, even if it doesn't do anything to him).Ah right, I'm just pointing out they really keep thinking Servants can get transmuted to anything when that never happens.
And I'm pretty certain Enkidu can completely vaporize Kakine anyway considering his Enuma Elish is on the same level as Gilgamesh's AND Noble Phantasms explicitly fuck with the Soul of the user.
It spreads pretty quickly (covering an island in a relatively short timeframe, don't remember the exact context).
And at an exponential rate too, since each particle of DM may as well be its own Kakine.
And Kakine at that point also... doesn't really have a soul (or a mind at that) to affect. He's sentient gray goo.
You could also make the argument about Kakine adapting to the physiology of Servants being resistant with his DM, but that's a whole other discussion.
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